NO2 is nitrite, and it's toxic to fish but food for beneficial bacteria. This is a bit over simplified, but one good bacteria culture converts ammonia to nitrate and nitrite, and another one converts nitrite to nitrate. Nitrate (NO3, I think) is more stable than nitrite. A third bacteria digests the nitrate and turns it into plant food. Ammonia and nitrite are reactive, because they have too many or too few electrons; that makes them try to merge with other compounds. It's been quite a few decades since I attended chemistry classes, and this explanation should prove it.